First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

古太平洋板块俯冲-增生时限：饶河增生杂岩的地球化学和年代学制约   总被引：1，自引：1，他引：0  

韩伟  周建波 《岩石学报》2020,36(3):703-725

饶河杂岩作为那丹哈达增生杂岩的主体,是古太平洋板块西向俯冲的直接证据。饶河增生杂岩组成与增生过程的研究对限定古太平洋板块向欧亚大陆的俯冲与增生过程具有重要的指示意义。本文在野外地质调查和饶河大岱地区大比例尺填图基础上,明确了饶河杂岩主要由枕状玄武岩、辉长岩以及大洋板块沉积地层(OPS)组成,这些岩石均呈构造透镜体状分布在海沟沉积物中,并被中生代花岗质岩脉所穿切,因此为限定饶河增生杂岩的组成、增生和就位时代提供了关键制约。地球化学数据表明玄武岩具有洋岛玄武岩(OIB)的地球化学属性。LA-ICPMS锆石测试结果表明该地区玄武岩和辉长岩的形成时代分别为166±2Ma和214±5Ma,限定了饶河杂岩中镁铁质-超镁铁质岩石的形成时代为晚三叠世至中侏罗世。结合该区粉砂质泥岩和砂岩的沉积时代下限分别为167±3Ma和133±4Ma,表明饶河杂岩的增生时代为167～133Ma,此外样品的碎屑年龄信息表明基质的物源为邻近的佳木斯地块和中亚造山带东段,其中前寒武的碎屑年龄在中国东北的多个陆块均有出现,可能源于早前存在的前寒武纪基底。本文测得侵入饶河杂岩的2个二长花岗岩形成年龄分别为126±1Ma和105±2Ma,表明饶河杂岩中的花岗岩脉主要形成于两个阶段,其中较老的花岗岩侵入体进一步限定了饶河杂岩的最终就位时代为133Ma至126Ma,表明古太平洋板块在中侏罗世至早白垩世存在西向俯冲-增生作用,为古太平洋板块的构造演化提供了重要的制约。  相似文献   

赣南狮吼山硫铁多金属矿区花岗岩地球化学、年代学特征及其成因     

贺根文  路思明  彭琳琳  于长琦  李伟  刘翠辉 《吉林大学学报(地球科学版)》2020,50(5):1491-1504

狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床，伴生W、Cu、Au多种成矿元素，成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期，为研究成矿岩体的侵位时代、岩石成因及与成矿的关系，本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征，属高钾钙碱性系列花岗岩；轻重稀土元素分馏明显，均为右倾型，弱Eu负异常，以富集Cs、Rb、Th、U、Pb，亏损Ba、Nb、Sr、和Ti等元素为主要特征，属于低Ba-Sr壳源花岗岩类；锆石具较好晶形，具典型岩浆锆石特征，利用LA-ICP-MS进行U-Pb测年，获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8），加权平均年龄为（162.4±1.4）Ma（MSWD=1.4），谐和年龄与加权平均年龄在误差范围内高度一致，表明茶山迳复式岩体侵位于燕山早期中侏罗世；综合考虑岩体矿物组合、主微量元素及高分异特征，认为其成因分类应属于S型花岗岩；对比中国花岗岩成矿元素平均含量，茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量，可同时为成矿作用提供热源、流体及物质。  相似文献   

Strategies towards robust interpretations of in situ zircon Lu-Hf isotope analyses     

《地学前缘(英文版)》2020,11(3):843-853

The combination of U-Pb and Lu-Hf compositions measured in zircon crystals is a remarkably powerful isotopic couplet that provides measures on both the timing of mineral growth and the radiogenic enrichment of the source from which the zircon grew.The U-Pb age documents the timing of zircon crystallization/recrystallization and Hf isotopes inform on the degree to which the host melt was derived from a radiogenic reservoir(e.g.depleted mantle) versus an unradiogenic reservoir(e.g.ancient continental crust),or some mixture of these sources.The ease of generating large quantities of zircon U-Pb and Lu-Hf data has been in large part facilitated by instrument advances.However,the dramatic increase in time constrained zircon Lu-Hf analyses in the Earth science community has brought to the fore the importance of careful data collection and reduction workflows,onto which robust geological interpretations may be based.In this work,we discuss the fundamentals of Lu-Hf isotopes in zircon,which then allows us to provide a robust,accessible,methodology for the assessment of data quality.Additionally,we discuss some novel techniques for:data visualization—that facilitates better transparency of data interpretation;integration of geographic information—that may reveal spatial trends where temporal trends were only apparent before;and some novel statistical evaluation tools—that may provide more rigorous interand intra-sample comparisons.  相似文献   

Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS     

Yu Liu  Qiu‐Li Li  Guo‐Qiang Tang  Xian‐Hua Li 《Geostandards and Geoanalytical Research》2020,44(3):421-437

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.  相似文献   

西准噶尔红山地区晚古生代赞岐岩锆石U Pb年代学、地球化学特征及其地质意义   总被引：1，自引：0，他引：1  

马飞宙  陈宣华  徐盛林  马芬  韩乐乐  丁伟翠  王叶 《地质学报》2020,94(5):1462-1481

中亚造山带西部西准噶尔地区红山花岗岩体内部发育多期似岩墙状安山质暗色条带,LA-ICP-MS锆石U-Pb同位素定年和岩石化学与同位素分析表明,它们具有不同的形成年龄、相同的源区和相似的形成过程。其中,具有不规则状或环状形态的暗色条带,其锆石U-Pb年龄为319.1±2.9 Ma和313.3±2.4 Ma,远大于红山岩体花岗岩锆石结晶年龄(305～301Ma),可能是红山岩体侵位过程中所捕掳的围岩;具有线性展布特征的安山质暗色条带,其锆石U-Pb年龄为295±2Ma,形成于红山岩体侵位之后,构成伸展岩墙群。红山岩体中的安山质暗色条带和线状岩墙群具有相似的岩石化学组成,富SiO_2(56.48%～63.09%)、MgO(3.56%～6.31%),具有高的Mg#值(51.74～62.40)及Na_2O/K_2O值(1.34～3.43);球粒陨石标准化稀土元素(REE)配分模式呈明显的右倾型,富集轻稀土元素(LREE)和大离子亲石元素(LILE)Rb、K、Ba、U、Sr,亏损高场强元素(HFSE)Th、Nb、Ce、P和重稀土元素,具较弱的负铕异常;其同位素组成特征为(~(87 )Sr/~(86 )Sr)i=0.703295～0.703620,(~(143) Nd/~(144) Nd)i=0.512612～0.512618,εNd(t)=6.91～7.62,(~(206) Pb/~(204) Pb)t为17.6883～17.9876,(~(207) Pb/~(204) Pb)t为15.5313～15.5686,(~(208)Pb/~(204)Pb)t为37.4460～38.0581。它们具有与赞岐岩类似的地球化学特征,总体表现出与弧岩浆作用相关的地球化学特征,可能具有共同的物质来源,为准噶尔洋板片俯冲消减后同一地幔源区在不同阶段的产物。其中,形成于弧岩浆作用时期的赞岐岩(319～313 Ma),构成与岛弧花岗岩类伴生的环状似岩墙状安山质暗色条带;形成于后造山伸展岩浆作用晚期的赞岐岩(～295Ma),构成与达拉布特左行走滑作用相关的陆内伸展岩墙群。安山质暗色条带(岛弧火山作用)、红山岩体(后造山伸展)和线状岩墙群(陆内伸展)记录了西准噶尔红山地区洋陆转换的全过程。  相似文献   

A shift in eruption mode of Hekla volcano,Iceland, 3000 years ago: two-coloured Hekla tephra series,characteristics, dispersal and age     

GUDRÚN LARSEN  Bryndís G. Róbertsdóttir  Bergrún A. Óladóttir  JÓN EIRÍKSSON 《第四纪科学杂志》2020,35(1-2):143-154

Hekla volcano is a major producer of large, widespread silicic tephras. About 3000 years ago, the dominant eruption mode shifted from infrequent large (>1 km³) to more frequent moderate (<1 km³) eruptions. In the following two millennia ≥20 explosive silicic-to-intermediate eruptions occurred, and six or more basaltic. Three categories can be identified with dacite/andesite to basaltic andesite in the oldest eruptions through basaltic andesite to basalt in the youngest eruptions. Ten tephra layers of the first category have distinct field characteristics: a pale lower unit and a dark upper unit (two coloured or TC-layers). Colour separation is sharp indicating a stratified magma chamber origin. The lower unit is dominantly andesitic (61–63% SiO₂), while the upper unit is basaltic andesite (53–57% SiO₂). Volumes of the eight largest TC-layers range from 0.2 to 0.7 km³ as freshly fallen. Radiocarbon and soil accumulation rate dates constrain the TC-layers to between 3000 and 2200 years ago. Two of these (~2890 and ~2920 b2k) are likely to occur overseas. Low SiO₂ in the last erupted tephra of the TC-layers is comparable to that of historical Hekla lavas, implying a final effusive phase. The Hekla edifice may, consequently, be younger than 3000 years.  相似文献   

扎格罗斯前陆盆地晚中新世快速剥露证据——来自磷灰石(U- Th)/He的约束     

李佳纬  孙继敏  吕丽星  张志亮  田晟辰  曹萌萌  李有生  苏柏 《地质学报》2020,94(12):3674-3688

伊朗扎格罗斯造山带是世界上最年轻的造山带之一，前人对其构造演化历史的研究尚存争议。前陆盆地蕴藏着丰富的造山带热史信息，为研究造山带的隆升和剥露历史提供了重要途径。本研究选取位于扎格罗斯前陆盆地前缘中部的Kuh- E Bedush向斜和Kuh- E Murdeh向斜翼部出露的第三纪陆相红层(Agha Jari组)为研究对象，共采集11个粗砂岩样品进行磷灰石(U- Th)/He测试分析。11个样品共得到38个单颗粒年龄，年龄区间为0. 8~79. 9Ma。大部分样品的单颗粒年龄比较分散，表明这些样品没有发生完全热重置。相反，位于Murdeh向斜剖面最底部的样品，(U- Th)/He年龄小于其对应的地层年龄，并且集中分布在8. 3~6. 8Ma，表明该样品发生了完全重置并记录了最后一次剥露事件的时间。因此，我们认为扎格罗斯前陆盆地于晚中新世~7. 5 Ma经历了一期快速剥露事件。此外，我们发现未重置的(U- Th)/He年龄大致分布在四个时间段：晚白垩纪—早古新世、早—中始新世、渐新世、早—中中新世。根据所得热年龄并结合前人研究设定了三种不同的热史，正演模拟结果与实际样品拟合较好，由此推断出前陆中部Agha Jari陆相红层沉积物可能来自于：①晚白垩世以来以蛇绿岩套为主的仰冲体持续剥露；②萨南达季- 锡尔詹变质带(SSZ)渐新世和中新世逐渐加速的剥露；③渐新世末堆积在仰冲体之上的同造山期砾岩，在中新世的大规模逆冲作用下重新剥露。  相似文献   

东昆仑夏日哈木退变质榴辉岩地球化学、年代学特征及其地质意义     

郭峰  王盘喜  王振宁  冯乃琦 《沉积与特提斯地质》2020,40(4):45-55

本文对东昆仑夏日哈木退变质榴辉岩开展岩石地球化学和年代学研究，探讨其原岩性质和构造背景。岩石SiO₂含量为46.77%~49.31%，Al₂O₃含量为13.6%~14.6%，TiO₂含量为0.93%~2.29%，全碱（K₂O+Na₂O）含量为1.61%~2.66%，原岩属亚碱性玄武岩系列中的拉斑玄武岩。（La/Yb）_N=0.98~1.63，（La/Sm）_N=0.98~1.41，δEu=1.10~1.28，稀土元素球粒陨石标准化图呈弱Eu正异常的右倾型，岩石相对富集大离子亲石元素Rb、Ba和不相容元素U，相对亏损高场强元素Zr、Hf，Hf/Th=0.59~0.97，Th/Yb=0.13~0.27，显示其原岩具E-MORB特征。退变质榴辉岩的锆石Th/U比值为0.002~0.091，为变质成因锆石，其锆石SIMS U-Pb年龄为414.2 ±7.3 Ma，代表了退变质榴辉岩的峰变质年龄，结合区域地质背景，认为该岩石形成于早泥盆世早期由碰撞作用向碰撞后伸展作用转换的构造环境。  相似文献   

海洋气团对沿海城市大气环境影响与识别研究     

石红旗  王霄曈  张昊阳  石博欣  张睿 《海洋科学》2018,42(12):100-108

本研究通过识别海洋气团特征及沿海城市大气受到海洋气团的影响方式与程度,为评价沿海城市空气环境质量提供科学依据。以青岛市为例,收集大气气溶胶样品中放射性核素~(210)Pb、40K数据及采集时段当地大气颗粒物数据;分析~(210)Pb活度浓度与气溶胶颗粒物浓度变化;对当地当时大气气团进行溯源分析。研究表明:(1)研究期间青岛沿岸地区2015年4月至2016年6月与2016年6月至2017年6月大气污染特征显著不同,前者~(210)Pb活度浓度与污染颗粒物浓度显著相关,而后者~(210)Pb活度浓度与污染颗粒物无相关关系;(2)穿越海洋的陆地气团呈现出高活度浓度、低颗粒物浓度的特征;来自海洋气团的气溶胶呈现出低活度浓度、低颗粒物浓度的特征;(3)海洋气团气溶胶中~(210)Pb活度浓度较低。临近大陆的海洋(黄海、东海)上层大气受到大陆气团的影响,其海洋气团的特征有所减弱。~(210)Pb活度浓度、颗粒物浓度(PM2.5)可作为判断海洋气团的指标,识别"来自海洋的气团"与"经过海洋的气团"。  相似文献